The family of polymers is extraordinarily large and varied. There are, however, some fairly broad and basic approaches that can be followed when designing or fabricating a product out of polymers or, more commonly, polymers compounded with other ingredients. The type of fabrication process to be adopted depends on the properties and characteristics of the polymer and on the shape and form of the final product.
In the broad classification of plastics there are two generally accepted categories: thermoplastic resins and thermosetting resins.
Thermoplastic resins consist of long polymer molecules, each of which may or may not have side chains or groups. The side chains or groups, if present, are not linked to other polymer molecules (i.e., are not cross-linked). Thermoplastic resins, usually obtained as a granular polymer, can therefore be repeatedly melted or solidified by heating or cooling. Heat softens or melts the material so that it can be formed; subsequent cooling then hardens or solidifies the material in the given shape. No chemical change usually takes place during this shaping process.
In thermosetting resins the reactive groups of the molecules from cross-links between the molecules during the fabrication process. The cross-linked or "cured" material cannot be softened by heating.
Thermoset materials are usually supplied as a partially polymerized molding compound or as a liquid monomer�polymer mixture. In this uncured condition they can be shaped with or without pressure and polymerized to the cured state with chemicals or heat.
With the progress of technology the demarcation between thermoplastic and thermoset processing has become less distinct. For thermosets processes have been developed which make use of the economic processing characteristics or thermoplastics. For example, cross-linked polyethylene wire coating is made by extruding the thermoplastic polyethylene, which is then cross-linked (either chemically or by irradiation) to form what is actually a thermoset material that cannot be melted again by heating.
More recently, modified machinery and molding compositions have become available to provide the economics of thermoplastic processing to thermosetting materials. Injection molding of phenolics and other thermosetting materials are such examples. Nevertheless, it is still a widespread practice in industry to distinguish between thermoplastic and thermosetting resins.
Compression and transfer molding are the most common methods of processing thermosetting plastics. For thermoplastics, the more important processing techniques are extrusion, injection, blow molding, and calendaring; other processes are thermoforming, slush molding, and spinning.
Tooling for plastics processing defines the shape of the part. It falls into two major categories, molds and dies. A mold is used to form a complete three-dimensional plastic part. The plastics processes that use molds are compression molding, injection molding, blow molding, thermoforming, and reaction injection molding (RIM). A die, on the other hand, is used to form two of the three dimensions of a plastic part. The third dimension, usually thickness or length, is controlled by other process variables.
The plastics processes that use dies are extrusion and thermoforming. Many plastics processes do not differentiate between the terms mold and die. Molds, however, are the most predominant form of plastics tooling.
Types of Molds for Plastic Processing Equipment
The basic types of mold, regardless of whether they are compression, injection, transfer, or even blow molds, are usually classified by the type and number of cavities they have. For example, Figure below illustrates three mold types: (a) single-cavity, (b) dedicated multiple-cavity, and (c) family multiple cavity.
Single-cavity mold represents one of the simplest mold concepts. This design lends itself to low-volume production and to large plastic part designs. The multiple-cavity molds may be of two types. A dedicated multiple-cavity mold has cavities that produce the same part. This type of mold is very popular because it is easy to balance the plastic flow and establish a controlled process. In a family multiple-cavity mold , each cavity may produce a different part. Historically, family mold designs were avoided because of difficulty in filling uniformly; however, recent advances in mold making and gating technology make family molds appealing. This is the case especially when a processor has a multiple-part assembly and would like to keep inventories balanced.
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Types of Dies for Plastic Processing Equipment
Within the plastics industry, the term die is most often applied to the processes of extrusion (see EXTRUSION). Extrusion dies may be categorized by the type of product being produced (e.g., film, sheet, profile, or coextrusion), but they all have some common features as described below.
1. Steel. The extrusion process being continuous, both erosion and corrosion are significant factors.
Hence the dies must be made of a high-quality tool steel, hardened so that the areas that contact the plastic material do not erode. Additionally, many dies have a dense, hard chrome plating in the area where plastic melt contacts the die.
2. Heaters. Extrusion dies are to be heated in order to maintain a melt flow condition for the plastic material. Most of the heaters are cartridge-type elements that slip fit into the die at particular locations. In addition to the heaters, the dies have to accommodate temperature sensors, such as thermocouples.
3. Melt Pressure. Many sophisticated dies are equipped with sensors that monitor melt pressure. This allows the processor to better monitor ad control the process.
4. Parting Line. Large extrusion dies must be able to separate at the melt flow line for easier fabrication and maintenance. Smaller extrusion dies may not have a parting area, because they can be constructed in one piece.
5. Die Swell Compensation. The polymer melt swells when it exits the die, as explained previously.
This die swell is a function of the type of plastic material, the melt temperature, the melt pressure, and the die configuration. The die must be compensated for die swell so that the extruded part has the corrected shape and dimensions. Molds and dies for different fabrication processes will be
described later in more detail when the processes are discussed in coming posts on our site.
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